Paper Published: Ultrathin inorganic molecular nanowire based on polyoxometalates

Authors

Z. Zhang, T. Murayama, M. Sadakane, H. Ariga, N. Yasuda, N. Sakaguchi, K. Asakura, W. Ueda

“Ultrathin inorganic molecular nanowire based on polyoxometalates”, Nature commun., 2015, 6, open access (Hokkaido University & Kanagawa University)

Abstract

The development of metal oxide-based molecular wires is important for fundamental research and potential practical applications. However, examples of these materials are rare. Here we report an all-inorganic transition metal oxide molecular wire prepared by disassembly of larger crystals. The wires are comprised of molybdenum(VI) with either tellurium(IV) or selenium(IV): {(NH4)2[XMo6O21]}n (X=tellurium(IV) or selenium(IV)). The ultrathin molecular nanowires with widths of 1.2 nm grow to micrometre-scale crystals and are characterized by single-crystal X-ray analysis, Rietveld analysis, scanning electron microscopy, X-ray photoelectron spectroscopy, ultraviolet-visible spectroscopy, thermal analysis and elemental analysis. The crystals can be disassembled into individual molecular wires through cation exchange and subsequent ultrasound treatment, as visualized by atomic force microscopy and transmission electron microscopy. The ultrathin molecular wire-based material exhibits high activity as an acid catalyst, and the band gap of the molecular wire-based crystal is tunable by heat treatment.

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Project Coordinator: Professor Emiel Hensen, E.J.M.Hensen@TUE.NL Project Manager: Dr Gabriela Dima, G.E.Dima@TUE.NL

NOVACAM is a coordinated EU-Japan project supported by the European Union and the Japan Science and Technology Agency. This project has received funding from the European Union’s Seventh Framework Programme for research, technological development and demonstration under grant agreement no 604319.